Quantization of the electromagnetic field
After quantization of the electromagnetic field, the EM (electromagnetic) field consists of discrete energy parcels, photons. Photons are massless particles of definite energy, definite momentum, and definite spin.
In order to explain the photoelectric effect, Einstein assumed heuristically in 1905 that an electromagnetic field consists of parcels of energy hν, where h is Planck's constant. In 1927 Paul A. M. Dirac was able to weave the photon concept into the fabrics of the new quantum mechanics and to describe the interaction of photons with matter. He applied a technique which is now generally called second quantization, although this term is somewhat of a misnomer for EM fields, because they are, after all, solutions of the classical Maxwell equations. In Dirac's theory the fields are quantized for the first time and it is also the first time that Planck's constant enters the expressions. In its original work, Dirac took the phases of the different EM modes (Fourier components of the field) and the mode energies as dynamic variables to quantize (i.e., he reinterpreted them as operators and postulated commutation relations between them). At present it is more common to quantize the Fourier components of the vector potential. This is what will be done below.
A quantum mechanical photon state |k,μ〉 belonging to mode (k,μ) will be introduced. It will be shown that it has the following properties
These equations say respectively: a photon has zero rest mass; the photon energy is hν=hc|k| (k is the wave vector, c is speed of light); its electromagnetic momentum is ℏk [ℏ=h/(2π)]; the polarization μ=±1 is the eigenvalue of the z-component of the photon spin.
 Second quantization
Second quantization starts with an expansion of a scalar of vector field (or wave functions) in a basis consisting of a complete set of functions. These expansion functions depend on the coordinates of a single particle. The coefficients multiplying the basis functions are interpreted as operators and (anti)commutation relations between these new operators are imposed, commutation relations for bosons and anticommutation relations for fermions (nothing happens to the basis functions themselves). By doing this, the expanded field is converted into a fermion or boson operator field. The expansion coefficients have been promoted from ordinary numbers to operators, creation and annihilation operators. A creation operator creates a particle in the corresponding basis function and an annihilation operator annihilates a particle in this function.
In the case of EM fields the required expansion of the field is the Fourier expansion.
 Electromagnetic field and vector potential
- See Fourier expansion electromagnetic field for more details.
As the term suggests, an EM field consists of two vector fields, an electric field E(r,t) and a magnetic field B(r,t). Both are time-dependent vector fields that in vacuum depend on a third vector field A(r,t) (the vector potential) through
where the wave vector k gives the propagation direction of the corresponding Fourier component (a polarized monochromatic wave) of A(r,t); the length of the wave vector is |k| = 2πν/c = ω/c, with ν the frequency of the mode. The components of the vector k have discrete values (a consequence of the boundary condition that A has the same value on opposite walls of the box),
The two unit vectors e(μ) ("polarization vectors") are perpendicular to k. They are related to the orthonormal Cartesian vectors ex and ey through a unitary transformation,
The k-th Fourier component of A is a vector perpendicular to k and hence is a linear combination of e(1) and e(−1). The superscript μ indicates a component along e(μ). The Coulomb gauge is imposed,
which makes A into a transverse field.
Clearly, the (discrete infinite) set of Fourier coefficients and are variables defining the vector potential. In the following they will be promoted to operators.
 Quantization of EM field
The best known example of quantization is the replacement of the time-dependent linear momentum of a particle by the rule
Note that Planck's constant is introduced here and that the time-dependence of the classical expression is not taken over in the quantum mechanical operator (this is true in the so-called Schrödinger picture).
subject to the boson commutation relations
The square brackets indicate a commutator, defined by
for any two quantum mechanical operators A and B. The introduction of Planck's constant is essential in the transition from a classical to a quantum theory. The factor (2ωVε0)−½ is introduced to give the Hamiltonian (energy operator) a simple form, see below.
The quantized fields (operator fields) are the following
where ω = c |k| = ck.
 Hamiltonian of the field
The classical Hamiltonian has the form
Substitution of the field operators into the classical Hamiltonian gives the Hamilton operator of the EM field,
By the use of the commutation relations the second line follows from the first. Note again that ℏω = hν = ℏc|k| and remember that ω depends on k, even though it is not explicit in the notation. The notation ω(k) could have been introduced, but is not common as it clutters the equations.
 Digression: harmonic oscillator
The second quantized treatment of the one-dimensional quantum harmonic oscillator is a well-known topic in quantum mechanical courses. We digress and say a few words about it. The harmonic oscillator Hamiltonian has the form
where ω ≡ 2πν is the fundamental frequency of the oscillator. The ground state of the oscillator is designated by | 0 〉 and is referred to as vacuum state. It can be shown that is an excitation operator, it excites from an n fold excited state to an n+1 fold excited state:
Since harmonic oscillator energies are equidistant, the n-fold excited state | n〉 can be looked upon as a single state containing n particles (sometimes called vibrons) all of energy hν. These particles are bosons. For obvious reason the excitation operator is called a creation operator.
From the commutation relation follows that the Hermitian adjoint de-excites:
For obvious reason the de-excitation operator is called an annihilation operator.
By mathematical induction the following "differentiation rule", that will be needed later, is easily proved,
Suppose now we have a number of non-interacting (independent) one-dimensional harmonic oscillators, each with its own fundamental frequency ωi. Because the oscillators are independent, the Hamiltonian is a simple sum:
Making the substitution
we see that the Hamiltonian of the EM field can be looked upon as a Hamiltonian of independent oscillators of energy ω = |k| c and oscillating along direction e(μ) with μ=1,−1.
 Photon states
The quantized EM field has a vacuum (no photons) state | 0 〉. The application to it of, say,
gives a quantum state of m photons in mode (k,μ) and n photons in mode (k', μ'). The proportionality symbol is used because the state on the left-hand is not normalized to unity, whereas the state on the right-hand may be normalized.
is the number operator. When acting on a quantum mechanical photon state, it returns the number of photons in mode (k,μ). This also holds when the number of photons in this mode is zero, then the number operator returns zero. To show the action of the number operator on a one-photon ket, we consider
i.e., a number operator of mode (k,μ) returns zero if the mode is unoccupied and returns unity if the mode is singly occupied. To consider the action of the number operator of mode (k, μ) on a n-photon ket of the same mode, we drop the indices k and μ and consider
Use the "differentiation rule" introduced earlier and it follows that
A photon state is an eigenstate of the number operator. This is why the formalism described here, is often referred to as the occupation number representation.
 Photon energy
Earlier the Hamiltonian,
was introduced. The zero of energy can be shifted, which leads to an expression in terms of te number operator,
The effect of H on a single-photon state is
Apparently, the single-photon state is an eigenstate of H and ℏω = hν is the corresponding energy. In the very same way
 Example photon density
In this article the electromagnetic energy density was computed that a 100kW radio station creates in its environment; at 5 km from the station it was estimated to be 2.1·10−10 J/m3. Is quantum mechanics needed to describe the broadcasting of this station?
The classical approximation to EM radiation is good when the number of photons is much larger than unity in the volume
where λ is the length of the radio waves. In that case quantum fluctuations are negligible and cannot be heard.
Suppose the radio station broadcasts at ν = 100 MHz, then it is sending out photons with an energy content of νh = 1·108× 6.6·10−34 = 6.6·10−26 J, where h is Planck's constant. The wavelength of the station is λ = c/ν = 3 m, so that λ/(2π) = 48 cm and the volume is 0.111 m3. The energy content of this volume element is 2.1·10−10 × 0.111 = 2.3 ·10−11 J, which amounts to
- 3.5 ·1012 photons per
Obviously, 3.5 ·1012 is much larger than one and hence quantum effects do not play a role; the waves emitted by this station are well into the classical limit, even when it plays non-classical music, for instance of Led Zepplin.
 Photon momentum
Introducing the Fourier expansion of the electromagnetic field into the classical form
The term 1/2 could be dropped, because when one sums over the allowed k, k cancels with −k. The effect of PEM on a single-photon state is
Apparently, the single-photon state is an eigenstate of the momentum operator, and ℏk is the eigenvalue (the momentum of a single photon).
 Photon mass
The photon having non-zero linear momentum, one could imagine that it has a non-vanishing rest mass m0, which is its mass at zero speed. However, we will now show that this is not the case: m0 = 0.
and it follows that
so that m0 = 0.
 Photon spin
The photon can be assigned a triplet spin with spin quantum number S = 1. This is similar to, say, the nuclear spin of the 14N isotope, but with the important difference that the state with MS = 0 is zero, only the states with MS = ±1 are non-zero.
Define spin operators:
The products between the two orthogonal unit vectors are dyadic products. The unit vectors are perpendicular to the propagation direction k (the direction of the z axis, which is the spin quantization axis).
The spin operators satisfy the usual angular momentum commutation relations
Indeed, use the dyadic product property
because ez is of unit length. In this manner,
By inspection it follows that
and therefore μ labels the photon spin,
Because the vector potential A is a transverse field, the photon has no forward (μ = 0) spin component.
- ↑ P. A. M. Dirac, The Quantum Theory of the Emission and Absorption of Radiation, Proc. Royal Soc. (London) A114, pp. 243–265, (1927) Online (pdf)
- ↑ The name derives from the second quantization of quantum mechanical wave functions. Such a wave function is a scalar field: the "Schrödinger field" and can be quantized in the very same way as electromagnetic fields. Since a wave function is derived from a "first" quantized Hamiltonian, the quantization of the Schrödinger field is the second time quantization is performed, hence the name.