Boltzmann constant

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The Boltzmann constant k (also kB) is the ratio of the molar gas constant R to Avogadro's constant NA. It can be thought of as the gas constant for a single molecule (or even for an arbitrary particle in a colloidal solution) rather than for a mole[1].

The Boltzmann constant is illustrated here in the equation for the translational kinetic energy of a simple particle in thermal equilibrium with its surroundings:[2]

 KE_\mathrm{avg} = \left(\frac{3}{2}\right) kT

Where KEavg is the average kinetic energy of the particle, k is the Boltzmann constant, and T is the temperature in kelvin.

For more info on this see the equipartition theorem.

According to NIST[3] the Boltzmann constant has a value of 1.3806504 x 10-23 J/K with a standard uncertainty of 0.0000024 x 10-23 J/K and a relative uncertainty of 1.7 x 10-6 (this is represented by the concise form 1.380 6504(24) x 10-23 J/K

The Boltzmann constant can also be represented in alternative units as 8.617385 x 10-5 eV/K

[edit] References

  1. Fundamentals of Physics, Fourth Edition by David Halliday, Robert Resnick, and Jearl Walker p582
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